Green Approach To Corrosion Inhibition Of Aluminium By Senna Auriculata Leaves Extract In 1 N NaOH Solution

A. Sirajunnisa, M.I.Fazal Mohamed, A. Subramania, B.R. Venkatraman

Abstract


Corrosion inhibition of aluminium in 1N NaOH by leaves extract of Senna auriculata (SL) was studied using chemical and electrochemical techniques at 30-60°C. It was found that the leaves of Senna auriculata inhibited the base induced corrosion of aluminium.The inhibition efficiency increases with increase in concentration of SL extract and reached the maximum of 76.2% but decrease with rise in temperature. The adsorption of SL on metal surface obeyed Langmuir adsorption isotherm. Polarization measurements showed that SL extract acted as mixed type inhibitor. The surface morphology of aluminium, in the absence and presence of SL extract in 1N NaOH solution, was studied using scanning electron microscopy. Results obtained from chemical and electrochemical techniques were in good agreement. Thermodynamic parameters such as activation energy and free energy of adsorption were calculated and given in kJ/mol.


Keywords


Aluminium corrosion, Corrosion inhibitors, Senna auriculata leaves extract, Langmuir adsorption isotherm, Mixed type inhibitor.

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